Sodium amide, commonly called sodamide, is the chemical compound with the formula NaNH2. This solid, which is dangerously reactive toward water, is white when pure, but commercial samples are typically gray due to the presence of small quantities of metallic iron from the manufacturing process. Such impurities do not usually affect the utility of the reagent. NaNH2 conducts electricity in the fused state, its conductance being similar to that of NaOH in a similar state. NaNH2 has been widely employed as a strong base in organic synthesis.
Sodium amide can be prepared by the reaction of sodium with ammonia gas,but it is usually prepared by the reaction in liquid ammonia using iron(III) nitrate as a catalyst. The reaction is fastest at the boiling point of the ammonia, c. −33 ¡ãC. An electride, [Na(NH3)6]+e-, is formed as an intermediate.
2 Na + 2 NH3¡ú 2 NaNH2 + H2 NaNH2 is a salt-like material and as such, crystallizes as an infinite polymer.The geometry about sodium is tetrahedral.In ammonia, NaNH2 forms conductive solutions, consistent with the presence of Na(NH3)6+ and NH2- anions.
Jinxiang chemical factory produces high quality sodium amide, it's mainly used in the industrial production of indigo, hydrazine, and sodium cyanide.It is the reagent of choice for the drying of ammonia (liquid or gaseous) and is also widely used as a strong base in organic chemistry, often in liquid ammonia solution. One of the main advantages to the use of sodamide is that it is an excellent base and rarely serves as a nucleophile. It is however poorly soluble and its use has been superseded by the related reagents such as sodium hydride, sodium bis(trimethylsilyl)amide (NaHMDS), and lithium diisopropylamide (LDA). |